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Single metal four-electron reduction by U(ii) and masked “U(ii)” compounds
The redox chemistry of uranium is dominated by single electron transfer reactions while single metal four-electron transfers remain unknown in f-element chemistry. Here we show that the oxo bridged diuranium(iii) complex [K(2.2.2-cryptand)](2)[{((Me(3)Si)(2)N)(3)U}(2)(μ-O)], 1, effects the two-elect...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8098655/ https://www.ncbi.nlm.nih.gov/pubmed/33996013 http://dx.doi.org/10.1039/d1sc00668a |