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Negative X-ray expansion in cadmium cyanide

Cadmium cyanide, Cd(CN)(2), is a flexible coordination polymer best studied for its strong and isotropic negative thermal expansion (NTE) effect. Here we show that this NTE is actually X-ray-exposure dependent: Cd(CN)(2) contracts not only on heating but also on irradiation by X-rays. This behaviour...

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Detalles Bibliográficos
Autores principales: Coates, Chloe S., Murray, Claire A., Boström, Hanna L. B., Reynolds, Emily M., Goodwin, Andrew L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8111741/
https://www.ncbi.nlm.nih.gov/pubmed/34846452
http://dx.doi.org/10.1039/d0mh01989e