Prebiotic access to enantioenriched glyceraldehyde mediated by peptides

A prebiotically plausible route to enantioenriched glyceraldehyde is reported via a kinetic resolution mediated by peptides. The reaction proceeds via a selective reaction between the l-peptide and the l-sugar producing an Amadori rearrangement byproduct and leaving d-glyceraldehyde in excess. Solub...

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Detalles Bibliográficos
Autores principales: Yu, Jinhan, Jones, Alexander X., Legnani, Luca, Blackmond, Donna G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115318/
https://www.ncbi.nlm.nih.gov/pubmed/34084433
http://dx.doi.org/10.1039/d1sc01250a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8115318/
https://www.ncbi.nlm.nih.gov/pubmed/34084433
http://dx.doi.org/10.1039/d1sc01250a

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