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Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions

Fluorine-containing moieties show significant effects in improving the properties of functional molecules. Consequently, efficient methods for installing them into target compounds are in great demand, especially those enabled by metal-free catalysis. Here we show a diazaphospholene-catalyzed hydrod...

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Detalles Bibliográficos
Autores principales: Zhang, Jingjing, Yang, Jin-Dong, Cheng, Jin-Pei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8121801/
https://www.ncbi.nlm.nih.gov/pubmed/33990577
http://dx.doi.org/10.1038/s41467-021-23101-3