Monitoring of the Pre-Equilibrium Step in the Alkyne Hydration Reaction Catalyzed by Au(III) Complexes: A Computational Study Based on Experimental Evidences

The coordination ability of the [(ppy)Au(IPr)](2+) fragment [ppy = 2-phenylpyridine, IPr = 1,3-bis(2,6-di-isopropylphenyl)-imidazol-2-ylidene] towards different anionic and neutral X ligands (X = Cl(−), BF(4)(−), OTf(−), H(2)O, 2-butyne, 3-hexyne) commonly involved in the crucial pre-equilibrium ste...

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Detalles Bibliográficos
Autores principales: Sabatelli, Flavio, Segato, Jacopo, Belpassi, Leonardo, Del Zotto, Alessandro, Zuccaccia, Daniele, Belanzoni, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122707/
https://www.ncbi.nlm.nih.gov/pubmed/33922177
http://dx.doi.org/10.3390/molecules26092445

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122707/
https://www.ncbi.nlm.nih.gov/pubmed/33922177
http://dx.doi.org/10.3390/molecules26092445

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