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Monitoring of the Pre-Equilibrium Step in the Alkyne Hydration Reaction Catalyzed by Au(III) Complexes: A Computational Study Based on Experimental Evidences
The coordination ability of the [(ppy)Au(IPr)](2+) fragment [ppy = 2-phenylpyridine, IPr = 1,3-bis(2,6-di-isopropylphenyl)-imidazol-2-ylidene] towards different anionic and neutral X ligands (X = Cl(−), BF(4)(−), OTf(−), H(2)O, 2-butyne, 3-hexyne) commonly involved in the crucial pre-equilibrium ste...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8122707/ https://www.ncbi.nlm.nih.gov/pubmed/33922177 http://dx.doi.org/10.3390/molecules26092445 |