Selenoxide Elimination Triggers Enamine Hydrolysis to Primary and Secondary Amines: A Combined Experimental and Theoretical Investigation

We discuss a novel selenium-based reaction mechanism consisting in a selenoxide elimination-triggered enamine hydrolysis. This one-pot model reaction was studied for a set of substrates. Under oxidative conditions, we observed and characterized the formation of primary and secondary amines as elimin...

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Detalles Bibliográficos
Autores principales: Ribaudo, Giovanni, Bortoli, Marco, Oselladore, Erika, Ongaro, Alberto, Gianoncelli, Alessandra, Zagotto, Giuseppe, Orian, Laura
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8125833/
https://www.ncbi.nlm.nih.gov/pubmed/34066723
http://dx.doi.org/10.3390/molecules26092770

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8125833/
https://www.ncbi.nlm.nih.gov/pubmed/34066723
http://dx.doi.org/10.3390/molecules26092770

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