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Covalency does not suppress O(2) formation in 4d and 5d Li-rich O-redox cathodes

Layered Li-rich transition metal oxides undergo O-redox, involving the oxidation of the O(2−) ions charge compensated by extraction of Li(+) ions. Recent results have shown that for 3d transition metal oxides the oxidized O(2−) forms molecular O(2) trapped in the bulk particles. Other forms of oxidi...

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Detalles Bibliográficos
Autores principales: House, Robert A., Marie, John-Joseph, Park, Joohyuk, Rees, Gregory J., Agrestini, Stefano, Nag, Abhishek, Garcia-Fernandez, Mirian, Zhou, Ke-Jin, Bruce, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8137948/
https://www.ncbi.nlm.nih.gov/pubmed/34016979
http://dx.doi.org/10.1038/s41467-021-23154-4