Catalytic asymmetric Nakamura reaction by gold(I)/chiral N,Nʹ-dioxide-indium(III) or nickel(II) synergistic catalysis

Intermolecular addition of enols and enolates to unactivated alkynes was proved to be a simple and powerful method for carbon-carbon bond formation. Up to date, a catalytic asymmetric version of alkyne with 1,3-dicarbonyl compound has not been realized. Herein, we achieve the catalytic asymmetric in...

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Detalles Bibliográficos
Autores principales: Hu, Xinyue, Tang, Xiaoxue, Zhang, Xiying, Lin, Lili, Feng, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8140141/
https://www.ncbi.nlm.nih.gov/pubmed/34021138
http://dx.doi.org/10.1038/s41467-021-23105-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8140141/
https://www.ncbi.nlm.nih.gov/pubmed/34021138
http://dx.doi.org/10.1038/s41467-021-23105-z

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