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Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds

Here we report that capping the molecule TTFtt (TTFtt = tetrathiafulvalene-2,3,6,7-tetrathiolate) with dialkyl tin groups enables the isolation of a stable series of redox congeners and facile transmetalation to Ni and Pd. TTFtt has been proposed as an attractive building block for molecular materia...

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Detalles Bibliográficos
Autores principales: Xie, Jiaze, Boyn, Jan-Niklas, Filatov, Alexander S., McNeece, Andrew J., Mazziotti, David A., Anderson, John S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8145528/
https://www.ncbi.nlm.nih.gov/pubmed/34084362
http://dx.doi.org/10.1039/c9sc04381k