A new hypervalent iodine(iii/v) oxidant and its application to the synthesis of 2H-azirines

The reaction of o-nitroiodobenzene and mCPBA in acetic acid was found to afford a novel hypervalent iodine compound, in the structure of which both iodine(iii) and iodine(v) moieties coexist. The nitro groups at the ortho phenyl positions were found to be crucial in stabilizing this uncommon structu...

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Detalles Bibliográficos
Autores principales: Zhang, Guangtao, Wang, Yuanxun, Xu, Jun, Sun, Jiyun, Sun, Fengxia, Zhang, Yilin, Zhang, Chenglin, Du, Yunfei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8145639/
https://www.ncbi.nlm.nih.gov/pubmed/34084348
http://dx.doi.org/10.1039/c9sc05536c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8145639/
https://www.ncbi.nlm.nih.gov/pubmed/34084348
http://dx.doi.org/10.1039/c9sc05536c

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