A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes

A 4-tetrafluoropyridinylthio group was suggested as a new photoredox-active moiety. The group can be directly installed on difluorostyrenes in a single step by the thiolene click reaction. It proceeds upon visible light catalysis with 9-phenylacridine providing various difluorinated sulfides as radi...

Descripción completa

Detalles Bibliográficos
Autores principales: Zubkov, Mikhail O., Kosobokov, Mikhail D., Levin, Vitalij V., Kokorekin, Vladimir A., Korlyukov, Alexander A., Hu, Jinbo, Dilman, Alexander D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8146146/
https://www.ncbi.nlm.nih.gov/pubmed/34123046
http://dx.doi.org/10.1039/c9sc04643g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8146146/
https://www.ncbi.nlm.nih.gov/pubmed/34123046
http://dx.doi.org/10.1039/c9sc04643g

Ejemplares similares