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Hydrogen and proton exchange at carbon. Imbalanced transition state and mechanism crossover
A recent remarkable study of the C–H oxidation of substituted fluorenyl-benzoates together with the transfer of a proton to an internal receiving group by means of electron transfer outer-sphere oxidants, in the noteworthy absence of hydrogen-bonding interactions, is taken as an example to uncover t...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8146334/ https://www.ncbi.nlm.nih.gov/pubmed/34084355 http://dx.doi.org/10.1039/c9sc05147c |