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Reversible reduction drives anion ejection and C(60) binding within an Fe(II)(4)L(6) cage
Fe(II)(4)L(6) tetrahedral cage 1 was prepared from a redox-active dicationic naphthalenediimide (NDI) ligand. The +20 charge of the cage makes it a good host for anionic guests, with no binding observed for neutral aromatic molecules. Following reduction by Cp(2)Co, the cage released anionic guests;...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8146419/ https://www.ncbi.nlm.nih.gov/pubmed/34084365 http://dx.doi.org/10.1039/c9sc05728e |