Site-selective redox isomerizations of furanosides using a combined arylboronic acid/photoredox catalyst system

In the presence of an arylboronic acid and a hydrogen atom transfer mediator under photoredox conditions, furanoside derivatives undergo site-selective redox isomerizations to 2-keto-3-deoxyfuranosides. Experimental evidence and computational modeling suggest that the transformation takes place by a...

Descripción completa

Detalles Bibliográficos
Autores principales: Dimakos, Victoria, Gorelik, Daniel, Su, Hsin Y., Garrett, Graham E., Hughes, Gregory, Shibayama, Hiromitsu, Taylor, Mark S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148048/
https://www.ncbi.nlm.nih.gov/pubmed/34084383
http://dx.doi.org/10.1039/c9sc05173b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148048/
https://www.ncbi.nlm.nih.gov/pubmed/34084383
http://dx.doi.org/10.1039/c9sc05173b

Ejemplares similares