Visible-light-induced intramolecular charge transfer in the radical spirocyclisation of indole-tethered ynones

Indole-tethered ynones form an intramolecular electron donor–acceptor complex that can undergo visible-light-induced charge transfer to promote thiyl radical generation from thiols. This initiates a novel radical chain sequence, based on dearomatising spirocyclisation with concomitant C–S bond forma...

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Detalles Bibliográficos
Autores principales: Ho, Hon Eong, Pagano, Angela, Rossi-Ashton, James A., Donald, James R., Epton, Ryan G., Churchill, Jonathan C., James, Michael J., O'Brien, Peter, Taylor, Richard J. K., Unsworth, William P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148050/
https://www.ncbi.nlm.nih.gov/pubmed/34123259
http://dx.doi.org/10.1039/c9sc05311e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148050/
https://www.ncbi.nlm.nih.gov/pubmed/34123259
http://dx.doi.org/10.1039/c9sc05311e

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