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Aldehydes and ketones influence reactivity and selectivity in nickel-catalysed Suzuki–Miyaura reactions
The energetically-favorable coordination of aldehydes and ketones – but not esters or amides – to Ni(0) during Suzuki–Miyaura reactions can lead either to exquisite selectivity and enhanced reactivity, or to inhibition of the reaction. Aryl halides where the C–X bond is connected to the same π-syste...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148322/ https://www.ncbi.nlm.nih.gov/pubmed/34123283 http://dx.doi.org/10.1039/c9sc05444h |