Cargando…

Aldehydes and ketones influence reactivity and selectivity in nickel-catalysed Suzuki–Miyaura reactions

The energetically-favorable coordination of aldehydes and ketones – but not esters or amides – to Ni(0) during Suzuki–Miyaura reactions can lead either to exquisite selectivity and enhanced reactivity, or to inhibition of the reaction. Aryl halides where the C–X bond is connected to the same π-syste...

Descripción completa

Detalles Bibliográficos
Autores principales:	Cooper, Alasdair K., Leonard, David K., Bajo, Sonia, Burton, Paul M., Nelson, David J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148322/ https://www.ncbi.nlm.nih.gov/pubmed/34123283 http://dx.doi.org/10.1039/c9sc05444h

Ejemplares similares

Inhibition of (dppf)nickel-catalysed Suzuki–Miyaura cross-coupling reactions by α-halo-N-heterocycles
por: Cooper, Alasdair K., et al.
Publicado: (2021)

Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
por: Guo, Lin, et al.
Publicado: (2019)

Base-Free Nickel-Catalysed DecarbonylativeSuzuki-Miyaura Coupling of Acid Fluorides
por: Malapit, Christian A., et al.
Publicado: (2018)

Experimental and computational insights into the mechanism of the copper(i)-catalysed sulfonylative Suzuki–Miyaura reaction
por: Hall, Callum G. J., et al.
Publicado: (2023)

Atomically dispersed palladium catalyses Suzuki–Miyaura reactions under phosphine-free conditions
por: Ding, Guodong, et al.
Publicado: (2020)

Nickel-metalated porous organic polymer for Suzuki–Miyaura cross-coupling reaction
por: Dong, Ying, et al.
Publicado: (2019)

Evaluation of P-bridged biaryl phosphine ligands in palladium-catalysed Suzuki–Miyaura cross-coupling reactions
por: Lamola, Jairus L., et al.
Publicado: (2021)

Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
por: Li, Yuqiang, et al.
Publicado: (2020)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
por: Schäfer, Philipp, et al.
Publicado: (2017)

Application of the Suzuki-Miyaura Reaction in the Synthesis of Flavonoids
por: Selepe, Mamoalosi A., et al.
Publicado: (2013)

Partition of the Reactive Species of the Suzuki–Miyaura Reaction between Aqueous and Micellar Environments
por: Ranaudo, Anna, et al.
Publicado: (2022)

Synthesis of α,β-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes
por: Rhlee, Joon Ho, et al.
Publicado: (2022)

Recent Developments in the Suzuki-Miyaura Reaction: 2010–2014
por: Maluenda, Irene, et al.
Publicado: (2015)

Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
por: Schäfer, Philipp, et al.
Publicado: (2018)

The Direct Mechanocatalytic Suzuki–Miyaura Reaction of Small Organic Molecules
por: Pickhardt, Wilm, et al.
Publicado: (2022)

Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes
por: Zhang, Guoqi, et al.
Publicado: (2022)

Ligand Steric Effects of α-Diimine Nickel(II) and Palladium(II) Complexes in the Suzuki–Miyaura Cross-Coupling Reaction
por: Talukder, Md Muktadir, et al.
Publicado: (2020)

Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments
por: Blangetti, Marco, et al.
Publicado: (2013)

Mechanistic Aspects of the Palladium‐Catalyzed Suzuki‐Miyaura Cross‐Coupling Reaction
por: D'Alterio, Massimo C., et al.
Publicado: (2021)

Highly E-Selective, Stereoconvergent Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Alkenyl Ethers
por: Ho, Guo-Ming, et al.
Publicado: (2019)

An Enantioselective Suzuki–Miyaura Coupling To Form Axially Chiral Biphenols
por: Pearce-Higgins, Robert, et al.
Publicado: (2022)

Cyano-borrowing reaction: nickel-catalyzed direct conversion of cyanohydrins and aldehydes/ketones to β-cyano ketone
por: Li, Zhao-Feng, et al.
Publicado: (2019)

Preparation of Synthetic and Natural Derivatives of Flavonoids Using Suzuki–Miyaura Cross-Coupling Reaction
por: Hurtová, Martina, et al.
Publicado: (2022)

Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling in a Green Alcohol Solvent for an Undergraduate Organic Chemistry Laboratory
por: Hie, Liana, et al.
Publicado: (2014)

A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water
por: Silva, Aires da Conceição, et al.
Publicado: (2013)

Suzuki–Miyaura cross coupling is not an informative reaction to demonstrate the performance of new solvents
por: Sherwood, James
Publicado: (2020)

Palladium catalyst imbedded in polymers of intrinsic microporosity for the Suzuki–Miyaura coupling reaction
por: Xu, Junwen, et al.
Publicado: (2018)

Scope and limitation of propylene carbonate as a sustainable solvent in the Suzuki–Miyaura reaction
por: Czompa, Andrea, et al.
Publicado: (2019)

Ultrasound-Assisted Hydrazine Reduction Method for the Preparation of Nickel Nanoparticles, Physicochemical Characterization and Catalytic Application in Suzuki-Miyaura Cross-Coupling Reaction
por: Ádám, Adél Anna, et al.
Publicado: (2020)

Peptide stapling by late-stage Suzuki–Miyaura cross-coupling
por: Gruß, Hendrik, et al.
Publicado: (2022)

Suzuki–Miyaura coupling of arylboronic acids to gold(iii)
por: Maity, Ayan, et al.
Publicado: (2015)

Synthesis of 3-hetarylpyrroles by Suzuki–Miyaura cross-coupling
por: Matyugina, Elena S., et al.
Publicado: (2020)

Enantio‐ and Diastereoselective Suzuki–Miyaura Coupling with Racemic Bicycles
por: Goetzke, F. Wieland, et al.
Publicado: (2019)

Palladium-catalyzed Suzuki-Miyaura coupling of thioureas or thioamides
por: Mai, Shaoyu, et al.
Publicado: (2019)

Reusable Pd-PolyHIPE for Suzuki–Miyaura Coupling
por: Ravbar, Miha, et al.
Publicado: (2022)

Supported Palladium Nanoparticles Synthesized by Living Plants as a Catalyst for Suzuki-Miyaura Reactions
por: Parker, Helen L., et al.
Publicado: (2014)

Regioselective Suzuki-Miyaura Reaction: Application to the Microwave-promoted Synthesis of 4,7-Diarylquinazolines
por: Kabri, Youssef, et al.
Publicado: (2010)

Design and Synthesis of Arylthiophene-2-Carbaldehydes via Suzuki-Miyaura Reactions and Their Biological Evaluation
por: Ali, Shaukat, et al.
Publicado: (2013)

Size-Dependent Catalytic Activity and Fate of Palladium Nanoparticles in Suzuki–Miyaura Coupling Reactions
por: Chatterjee, Sujit, et al.
Publicado: (2018)

Synthesis and Characterization of Biguanide and Biguanidium Surfactants for Efficient and Recyclable Application in the Suzuki–Miyaura Reaction
por: Fortun, Solène, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_gf508qm97br7i07c1t72jcdmqq