Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications

A synthetic strategy for the 2-phospha-1,3-butadiene derivatives [{(IPr)C(Ph)}P(cAAC(Me))] (3a) and [{(IPr)C(Ph)}P(cAAC(Cy))] (3b) (IPr = C{(NDipp)CH}(2), Dipp = 2,6-iPr(2)C(6)H(3); cAAC(Me) = C{(NDipp)CMe(2)CH(2)CMe(2)}; cAAC(Cy) = C{(NDipp)CMe(2)CH(2)C(Cy)}, Cy = cyclohexyl) containing a C[double...

Descripción completa

Detalles Bibliográficos
Autores principales: Sharma, Mahendra K., Blomeyer, Sebastian, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, Hinz, Alexander, van Gastel, Maurice, Ghadwal, Rajendra S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148328/
https://www.ncbi.nlm.nih.gov/pubmed/34123292
http://dx.doi.org/10.1039/c9sc05598c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148328/
https://www.ncbi.nlm.nih.gov/pubmed/34123292
http://dx.doi.org/10.1039/c9sc05598c

Ejemplares similares