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Rotaxane Pt(II)-complexes: mechanical bonding for chemically robust luminophores and stimuli responsive behaviour

We report an approach to rotaxanes in which the metal ion of a cyclometallated Pt(II) luminophore is embedded in the space created by the mechanical bond. Our results show that the interlocked ligand environment stabilises a normally labile Pt(II)–triazole bond against displacement by competing liga...

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Detalles Bibliográficos
Autores principales: Zhang, Zhihui, Tizzard, Graham J., Williams, J. A. Gareth, Goldup, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148368/
https://www.ncbi.nlm.nih.gov/pubmed/34123277
http://dx.doi.org/10.1039/c9sc05507j