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Effects of ring-strain on the ultrafast photochemistry of cyclic ketones

Ring-strain in cyclic organic molecules is well-known to influence their chemical reactivity. Here, we examine the consequence of ring-strain for competing photochemical pathways that occur on picosecond timescales. The significance of Norrish Type-I photochemistry is explored for three cyclic keton...

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Detalles Bibliográficos
Autores principales: Kao, Min-Hsien, Venkatraman, Ravi Kumar, Ashfold, Michael N. R., Orr-Ewing, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148387/
https://www.ncbi.nlm.nih.gov/pubmed/34123294
http://dx.doi.org/10.1039/c9sc05208a