Transition metal-free catalytic reduction of primary amides using an abnormal NHC based potassium complex: integrating nucleophilicity with Lewis acidic activation

An abnormal N-heterocyclic carbene (aNHC) based potassium complex was used as a transition metal-free catalyst for reduction of primary amides to corresponding primary amines under ambient conditions. Only 2 mol% loading of the catalyst exhibits a broad substrate scope including aromatic, aliphatic...

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Detalles Bibliográficos
Autores principales: Bhunia, Mrinal, Sahoo, Sumeet Ranjan, Das, Arpan, Ahmed, Jasimuddin, P., Sreejyothi, Mandal, Swadhin K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148392/
https://www.ncbi.nlm.nih.gov/pubmed/34123278
http://dx.doi.org/10.1039/c9sc05953a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148392/
https://www.ncbi.nlm.nih.gov/pubmed/34123278
http://dx.doi.org/10.1039/c9sc05953a

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