Cargando…

Sulfoxide-mediated oxidative cross-coupling of phenols

A metal-free, oxidative coupling of phenols with various nucleophiles, including arenes, 1,3-diketones and other phenols, is reported. Cross-coupling is mediated by a sulfoxide which inverts the reactivity of the phenol partner. Crucially, the process shows high selectivity for cross-versus homo-cou...

Descripción completa

Detalles Bibliográficos
Autores principales: He, Zhen, Perry, Gregory J. P., Procter, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8150100/
https://www.ncbi.nlm.nih.gov/pubmed/34123295
http://dx.doi.org/10.1039/c9sc05668h