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A borane-mediated palladium-catalyzed reductive allylic alkylation of α,β-unsaturated carbonyl compounds
The development of the palladium-catalyzed allylic alkylation of in situ generated boron enolates via tandem 1,4-hydroboration is reported. Investigation of the reaction revealed insights into specific catalyst electronic features as well as a profound leaving group effect that proved crucial for ac...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8150111/ https://www.ncbi.nlm.nih.gov/pubmed/34123302 http://dx.doi.org/10.1039/c9sc05970a |