Mechanisms of IR amplification in radical cation polarons

Break down of the Born–Oppenheimer approximation is caused by mixing of electronic and vibrational transitions in the radical cations of some conjugated polymers, resulting in unusually intense vibrational bands known as infrared active vibrations (IRAVs). Here, we investigate the mechanism of this...

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Detalles Bibliográficos
Autores principales: Kendrick, William J., Jirásek, Michael, Peeks, Martin D., Greetham, Gregory M., Sazanovich, Igor V., Donaldson, Paul M., Towrie, Michael, Parker, Anthony W., Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8150116/
https://www.ncbi.nlm.nih.gov/pubmed/34123299
http://dx.doi.org/10.1039/c9sc05717j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8150116/
https://www.ncbi.nlm.nih.gov/pubmed/34123299
http://dx.doi.org/10.1039/c9sc05717j

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