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Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation
An extremely bulky, symmetrical three-coordinate magnesium(i) complex, [{((TCHP)Nacnac)Mg}(2)] ((TCHP)Nacnac = [{(TCHP)NCMe}(2)CH](−), TCHP = 2,4,6-tricyclohexylphenyl) has been prepared and shown to have an extremely long Mg–Mg bond (3.021(1) Å) for such a complex. It was shown not to react with ei...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152598/ https://www.ncbi.nlm.nih.gov/pubmed/34109023 http://dx.doi.org/10.1039/d0sc00836b |