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Skeletal diversity in Pt- and Au-catalyzed annulations of allenedienes: dissecting unconventional mechanistic pathways

We describe the discovery of unprecedented annulation processes of 1,7-allenedienes, promoted by Pt or Au catalysts. These transformations revealed mechanistic pathways that had not been previously observed in reactions involving carbophilic catalysis. In particular, we have found that allenedienes...

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Detalles Bibliográficos
Autores principales: Nelson, Ronald, Calvelo, Martín, García-Fandiño, Rebeca, Lledós, Agustí, Ujaque, Gregori, Mascareñas, José L., López, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152626/
https://www.ncbi.nlm.nih.gov/pubmed/34122884
http://dx.doi.org/10.1039/d0sc00650e