Cargando…
Skeletal diversity in Pt- and Au-catalyzed annulations of allenedienes: dissecting unconventional mechanistic pathways
We describe the discovery of unprecedented annulation processes of 1,7-allenedienes, promoted by Pt or Au catalysts. These transformations revealed mechanistic pathways that had not been previously observed in reactions involving carbophilic catalysis. In particular, we have found that allenedienes...
Autores principales: | Nelson, Ronald, Calvelo, Martín, García-Fandiño, Rebeca, Lledós, Agustí, Ujaque, Gregori, Mascareñas, José L., López, Fernando |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152626/ https://www.ncbi.nlm.nih.gov/pubmed/34122884 http://dx.doi.org/10.1039/d0sc00650e |
Ejemplares similares
-
Anti-Markovnikov Intermolecular Hydroamination of
Alkenes and Alkynes: A Mechanistic View
por: Escorihuela, Jorge, et al.
Publicado: (2023) -
Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal
Geometry in Determining the Reaction Outcome
por: Casanova, Noelia, et al.
Publicado: (2016) -
Rhodium(III)-Catalyzed Intramolecular Annulations
of Acrylic and Benzoic Acids to Alkynes
por: F. Fernández, David, et al.
Publicado: (2019) -
Transition‐Metal‐Catalyzed Annulations Involving the Activation of C(sp(3))−H Bonds
por: Font, Marc, et al.
Publicado: (2021) -
Rhodium(III)-Catalyzed
Dearomatizing (3 + 2) Annulation
of 2-Alkenylphenols and Alkynes
por: Seoane, Andrés, et al.
Publicado: (2014)