Completing the triad: synthesis and full characterization of homoleptic and heteroleptic carbonyl and nitrosyl complexes of the group VI metals

Oxidation of M(CO)(6) (M = Cr, Mo, W) with the synergistic oxidative system Ag[WCA]/0.5 I(2) yields the fully characterized metalloradical salts [M(CO)(6)](+)˙[WCA](−) (weakly coordinating anion WCA = [F-{Al(OR(F))(3)}(2)](−), R(F) = C(CF(3))(3)). The new metalloradical cations with M = Mo and W sho...

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Detalles Bibliográficos
Autores principales: Bohnenberger, Jan, Schmitt, Manuel, Feuerstein, Wolfram, Krummenacher, Ivo, Butschke, Burkhard, Czajka, Jakub, Malinowski, Przemysław J., Breher, Frank, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152671/
https://www.ncbi.nlm.nih.gov/pubmed/34094047
http://dx.doi.org/10.1039/c9sc06445a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152671/
https://www.ncbi.nlm.nih.gov/pubmed/34094047
http://dx.doi.org/10.1039/c9sc06445a

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