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Completing the triad: synthesis and full characterization of homoleptic and heteroleptic carbonyl and nitrosyl complexes of the group VI metals
Oxidation of M(CO)(6) (M = Cr, Mo, W) with the synergistic oxidative system Ag[WCA]/0.5 I(2) yields the fully characterized metalloradical salts [M(CO)(6)](+)˙[WCA](−) (weakly coordinating anion WCA = [F-{Al(OR(F))(3)}(2)](−), R(F) = C(CF(3))(3)). The new metalloradical cations with M = Mo and W sho...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152671/ https://www.ncbi.nlm.nih.gov/pubmed/34094047 http://dx.doi.org/10.1039/c9sc06445a |