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Enhancing the selectivity of prolinamide organocatalysts using the mechanical bond in [2]rotaxanes

The synthesis of a pair of switchable interlocked prolinamides and their use as organocatalysts in three different enamine-activated processes are reported. A diacylaminopyridine moiety was incorporated into the thread for directing [2]rotaxane formation further allowing the association of complemen...

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Detalles Bibliográficos
Autores principales: Calles, María, Puigcerver, Julio, Alonso, Diego A., Alajarin, Mateo, Martinez-Cuezva, Alberto, Berna, Jose
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152698/
https://www.ncbi.nlm.nih.gov/pubmed/34094051
http://dx.doi.org/10.1039/d0sc00444h