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Enhancing the selectivity of prolinamide organocatalysts using the mechanical bond in [2]rotaxanes
The synthesis of a pair of switchable interlocked prolinamides and their use as organocatalysts in three different enamine-activated processes are reported. A diacylaminopyridine moiety was incorporated into the thread for directing [2]rotaxane formation further allowing the association of complemen...
Autores principales: | Calles, María, Puigcerver, Julio, Alonso, Diego A., Alajarin, Mateo, Martinez-Cuezva, Alberto, Berna, Jose |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152698/ https://www.ncbi.nlm.nih.gov/pubmed/34094051 http://dx.doi.org/10.1039/d0sc00444h |
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