A regioselectively 1,1′,3,3′-tetrazincated ferrocene complex displaying core and peripheral reactivity

Regioselective 1,1′,3,3′-tetrazincation [C–H to C–Zn(tBu)] of ferrocene has been achieved by reaction of a fourfold excess of di-t-butylzinc (tBu(2)Zn) with sodium 2,2,6,6-tetramethylpiperidide (NaTMP) in hexane solution manifested in the trimetallic iron–sodium–zinc complex [Na(4)(TMP)(4)Zn(4)(tBu)...

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Detalles Bibliográficos
Autores principales: Honeyman, Gordon W., Armstrong, David R., Clegg, William, Hevia, Eva, Kennedy, Alan R., McLellan, Ross, Orr, Samantha A., Parkinson, John A., Ramsay, Donna L., Robertson, Stuart D., Towie, Stephen, Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152701/
https://www.ncbi.nlm.nih.gov/pubmed/34094116
http://dx.doi.org/10.1039/d0sc01612h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152701/
https://www.ncbi.nlm.nih.gov/pubmed/34094116
http://dx.doi.org/10.1039/d0sc01612h

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