Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions

A single-electron transfer (SET) between tris(pentafluorophenyl)borane (B(C(6)F(5))(3)) and N,N-dialkylanilines is reported, which is operative via the formation of an electron donor–acceptor (EDA) complex involving π-orbital interactions as a key intermediate under dark conditions or visible-light...

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Detalles Bibliográficos
Autores principales: Aramaki, Yoshitaka, Imaizumi, Naoki, Hotta, Mao, Kumagai, Jun, Ooi, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152713/
https://www.ncbi.nlm.nih.gov/pubmed/34122888
http://dx.doi.org/10.1039/d0sc01159b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152713/
https://www.ncbi.nlm.nih.gov/pubmed/34122888
http://dx.doi.org/10.1039/d0sc01159b

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