Cargando…
Exploiting single-electron transfer in Lewis pairs for catalytic bond-forming reactions
A single-electron transfer (SET) between tris(pentafluorophenyl)borane (B(C(6)F(5))(3)) and N,N-dialkylanilines is reported, which is operative via the formation of an electron donor–acceptor (EDA) complex involving π-orbital interactions as a key intermediate under dark conditions or visible-light...
Autores principales: | Aramaki, Yoshitaka, Imaizumi, Naoki, Hotta, Mao, Kumagai, Jun, Ooi, Takashi |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152713/ https://www.ncbi.nlm.nih.gov/pubmed/34122888 http://dx.doi.org/10.1039/d0sc01159b |
Ejemplares similares
-
Exploiting the Electronic Tuneability of Carboranes as Supports for Frustrated Lewis Pairs
por: Benton, Amanda, et al.
Publicado: (2018) -
Reactions of Frustrated Lewis Pairs with Chloro‐Diazirines: Cleavage of N=N Double Bonds
por: Mandal, Dipendu, et al.
Publicado: (2022) -
On the Significance of Lone Pair/Lone Pair and Lone
Pair/Bond Pair Repulsions in the Cation Affinity and Lewis Acid/Lewis
Base Interactions
por: Valadbeigi, Younes, et al.
Publicado: (2018) -
Reactions of Diethylazo‐Dicarboxylate with Frustrated Lewis Pairs
por: Mandal, Dipendu, et al.
Publicado: (2022) -
Single‐Electron Transfer in Frustrated Lewis Pair Chemistry
por: Holtrop, Flip, et al.
Publicado: (2020)