Mechanistic basis for tuning iridium hydride photochemistry from H(2) evolution to hydride transfer hydrodechlorination

The photochemistry of metal hydride complexes is dominated by H(2) evolution, limiting access to reductive transformations based on photochemical hydride transfer. In this article, the innate H(2) evolution photochemistry of the iridium hydride complexes [Cp*Ir(bpy-OMe)H](+) (1, bpy-OMe = 4,4ʹ-dimet...

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Detalles Bibliográficos
Autores principales: Barrett, Seth M., Stratakes, Bethany M., Chambers, Matthew B., Kurtz, Daniel A., Pitman, Catherine L., Dempsey, Jillian L., Miller, Alexander J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152724/
https://www.ncbi.nlm.nih.gov/pubmed/34094109
http://dx.doi.org/10.1039/d0sc00422g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152724/
https://www.ncbi.nlm.nih.gov/pubmed/34094109
http://dx.doi.org/10.1039/d0sc00422g

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