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Mechanistic basis for tuning iridium hydride photochemistry from H(2) evolution to hydride transfer hydrodechlorination
The photochemistry of metal hydride complexes is dominated by H(2) evolution, limiting access to reductive transformations based on photochemical hydride transfer. In this article, the innate H(2) evolution photochemistry of the iridium hydride complexes [Cp*Ir(bpy-OMe)H](+) (1, bpy-OMe = 4,4ʹ-dimet...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152724/ https://www.ncbi.nlm.nih.gov/pubmed/34094109 http://dx.doi.org/10.1039/d0sc00422g |