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Late-stage C(sp(2))–H and C(sp(3))–H glycosylation of C-aryl/alkyl glycopeptides: mechanistic insights and fluorescence labeling

C(sp(3))–H and C(sp(2))–H glycosylations of structurally complex amino acids and peptides were accomplished through the assistance of triazole peptide-isosteres. The palladium-catalyzed peptide–saccharide conjugation provided modular access to structurally complex C-alkyl glycoamino acids, glycopept...

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Detalles Bibliográficos
Autores principales: Wu, Jun, Kaplaneris, Nikolaos, Ni, Shaofei, Kaltenhäuser, Felix, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152807/
https://www.ncbi.nlm.nih.gov/pubmed/34094117
http://dx.doi.org/10.1039/d0sc01260b