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Perfect Spherical Tetrahedral Metallo-Borospherene Ta(4)B(18) as a Superatom Following the 18-Electron Rule

[Image: see text] Cage-like metallo-borospherenes exhibit unique structures and bonding. Inspired by the newly reported smallest spherical trihedral metallo-borospherene D(3h) Ta(3)B(12)(–) (1), which contains two equivalent B(3) triangles interconnected by three B(2) units on the cage surface, we p...

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Detalles Bibliográficos
Autores principales: Zhang, Yu, Lu, Xiao-Qin, Yan, Miao, Li, Si-Dian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8153900/
https://www.ncbi.nlm.nih.gov/pubmed/34056252
http://dx.doi.org/10.1021/acsomega.1c00828