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Rollover Cyclometalation vs Nitrogen Coordination in Tetrapyridyl Anticancer Gold(III) Complexes: Effect on Protein Interaction and Toxicity
[Image: see text] In this work, a pair of gold(III) complexes derived from the analogous tetrapyridyl ligands H(2)biqbpy1 and H(2)biqbpy2 was prepared: the rollover, bis-cyclometalated [Au(biqbpy1)Cl ([1]Cl) and its isomer [Au(biqbpy2)Cl ([2]Cl). In [1](+), two pyridyl rings coordinate to the metal...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154207/ https://www.ncbi.nlm.nih.gov/pubmed/34056633 http://dx.doi.org/10.1021/jacsau.0c00104 |