Cargando…

A Unifying Bioinspired Synthesis of (−)-Asperaculin A and (−)-Penifulvin D

[Image: see text] The first syntheses of the isomeric dioxafenestrene natural products (−)-asperaculin A and (−)-penifulvin D are reported. Each target is formed selectively by choice of oxidant in a final divergent bioinspired Baeyer–Villiger (BV) reaction. Density functional theory calculations re...

Descripción completa

Detalles Bibliográficos
Autores principales: George, Ian R., López-Tena, Miguel, Sundin, Anders P., Strand, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155558/
https://www.ncbi.nlm.nih.gov/pubmed/33830776
http://dx.doi.org/10.1021/acs.orglett.1c00955