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A Unifying Bioinspired Synthesis of (−)-Asperaculin A and (−)-Penifulvin D
[Image: see text] The first syntheses of the isomeric dioxafenestrene natural products (−)-asperaculin A and (−)-penifulvin D are reported. Each target is formed selectively by choice of oxidant in a final divergent bioinspired Baeyer–Villiger (BV) reaction. Density functional theory calculations re...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155558/ https://www.ncbi.nlm.nih.gov/pubmed/33830776 http://dx.doi.org/10.1021/acs.orglett.1c00955 |