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1,1,4,4-Tetracyanobutadiene-Functionalized Anthracenes: Regioselectivity of Cycloadditions in the Synthesis of Small Near-IR Dyes

[Image: see text] Two small 1,1,4,4-tetracyanobutadiene-functionalized chromophores were obtained by careful leverage of the regioselectivity of the cycloaddition reaction of tetracyanoethylene with anthracene–ynamide derivatives, inducing either a [2 + 2] or a [4 + 2] Diels–Alder process. DFT calcu...

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Detalles Bibliográficos
Autores principales: Philippe, Clotilde, Bui, Anh Thy, Batsongo-Boulingui, Sabrinah, Pokladek, Ziemowit, Matczyszyn, Katarzyna, Mongin, Olivier, Lemiègre, Loïc, Paul, Frédéric, Hamlin, Trevor A., Trolez, Yann
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155560/
https://www.ncbi.nlm.nih.gov/pubmed/33635667
http://dx.doi.org/10.1021/acs.orglett.1c00136