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Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions

[Image: see text] In this paper, several Mn(I) complexes were applied as catalysts for the homogeneous hydrogenation of ketones. The most active precatalyst is the bench-stable alkyl bisphosphine Mn(I) complex fac-[Mn(dippe) (CO)(3)(CH(2)CH(2)CH(3))]. The reaction proceeds at room temperature under...

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Detalles Bibliográficos
Autores principales: Weber, Stefan, Brünig, Julian, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155567/
https://www.ncbi.nlm.nih.gov/pubmed/34054186
http://dx.doi.org/10.1021/acs.organomet.1c00161