Insight into the Alcohol-Free Ring-Opening Polymerization of TMC Catalyzed by TBD

We report herein a study on the alcohol-free, ring-opening polymerization of trimethylene carbonate (TMC) in THF, catalyzed by 1,5,7-triazabicyclo [4.4.0] ec-5-ene (TBD) with ratios n(TBD)/n(TMC) ranging between 1/20 and 1/400. In all cases, the reaction proceeds very rapidly, even faster than in th...

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Detalles Bibliográficos
Autores principales: Azemar, Fabrice, Gimello, Olinda, Pinaud, Julien, Robin, Jean-Jacques, Monge, Sophie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8156564/
https://www.ncbi.nlm.nih.gov/pubmed/34069275
http://dx.doi.org/10.3390/polym13101589

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8156564/
https://www.ncbi.nlm.nih.gov/pubmed/34069275
http://dx.doi.org/10.3390/polym13101589

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