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Reaction of chloroauric acid with histidine in microdroplets yields a catalytic Au–(His)(2) complex

An aqueous solution containing histidine (His, 100 μM) and chloroauric acid (HAuCl(4), 10 μM) is electrosprayed (−4.5 kV) from a capillary (50 μm in diameter) with N(2) nebulizing gas (120 psi). The resulting microdroplets entered a mass spectrometer with a 2 cm flight path. The mass spectrum record...

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Detalles Bibliográficos
Autores principales: Luo, Kai, Li, Jia, Cao, Yufei, Liu, Chengyuan, Ge, Jun, Chen, Hao, Zare, Richard N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157187/
https://www.ncbi.nlm.nih.gov/pubmed/34084419
http://dx.doi.org/10.1039/c9sc06221a