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Intra- and intermolecular Fe-catalyzed dicarbofunctionalization of vinyl cyclopropanes

Design and implementation of the first (asymmetric) Fe-catalyzed intra- and intermolecular difunctionalization of vinyl cyclopropanes (VCPs) with alkyl halides and aryl Grignard reagents has been realized via a mechanistically driven approach. Mechanistic studies support the diffusion of alkyl radic...

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Detalles Bibliográficos
Autores principales: Liu, Lei, Lee, Wes, Yuan, Mingbin, Acha, Chris, Geherty, Michael B., Williams, Brandon, Gutierrez, Osvaldo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157325/
https://www.ncbi.nlm.nih.gov/pubmed/34122819
http://dx.doi.org/10.1039/d0sc00467g