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Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))–H bond functionalisation

Herein we report the photophysical and photochemical properties of palladacycle complexes derived from 8-aminoquinoline ligands, commonly used auxiliaries in C–H activation. Spectroscopic, electrochemical and computational studies reveal that visible light irradiation induces a mixed LLCT/MLCT charg...

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Detalles Bibliográficos
Autores principales: Czyz, Milena L., Weragoda, Geethika K., Horngren, Tyra H., Connell, Timothy U., Gomez, Daniel, O'Hair, Richard A. J., Polyzos, Anastasios
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157331/
https://www.ncbi.nlm.nih.gov/pubmed/34084410
http://dx.doi.org/10.1039/c9sc05722f