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Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))–H bond functionalisation
Herein we report the photophysical and photochemical properties of palladacycle complexes derived from 8-aminoquinoline ligands, commonly used auxiliaries in C–H activation. Spectroscopic, electrochemical and computational studies reveal that visible light irradiation induces a mixed LLCT/MLCT charg...
Autores principales: | Czyz, Milena L., Weragoda, Geethika K., Horngren, Tyra H., Connell, Timothy U., Gomez, Daniel, O'Hair, Richard A. J., Polyzos, Anastasios |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157331/ https://www.ncbi.nlm.nih.gov/pubmed/34084410 http://dx.doi.org/10.1039/c9sc05722f |
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