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Heavy-atom tunnelling in Cu(ii)N(6) complexes: theoretical predictions and experimental manifestation
The degenerate rearrangement on Jahn–Teller distorted metal complexes is a promising reaction for the observation of significant heavy atom quantum mechanical tunnelling. Herein, a family of Cu(ii)–N(6) complexes are theoretically proven to exhibit rapid dynamical Jahn–Teller tunneling even close to...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157485/ https://www.ncbi.nlm.nih.gov/pubmed/34084343 http://dx.doi.org/10.1039/d0sc00160k |